MCM-41 molecular sieve: Preparation and application for removal of yellow reactive dye / Peneira molecular MCM-41: Preparação e aplicação para remoção de corante reativo amarelo
DOI:
https://doi.org/10.34117/bjdv.v7i5.30455Keywords:
Peneira molecular MCM-41, adsorção, corante amarelo reativo BF-3R, água residual.Abstract
Este trabalho apresenta a síntese da peneira molecular MCM-41, caracterização e avalia o potencial de remoção do corante amarelo reativo de uma solução aquosa. A peneira molecular MCM-41 foi sintetizada usando tratamento hidrotérmico a 150 oC por 96 h e caracterizada por difração de raios X (DRX), Fluorescência de raios X por energia dispersiva (FRX), espectroscopia na região do infravermelho (IV) e microscopia eletrônica de varredura (MEV). O processo de adsorção em batelada a 200 rpm por 24 h foi utilizado para avaliar o potencial da MCM-41 para a adsorção do corante com concentração inicial de corante 50 mg/L e temperatura de 25 oC. Um planejamento fatorial 22 foi utilizado para avaliar os principais efeitos dos valores de pH na faixa de 2,0 a 6,0 e massa (0,25 a 0,75 g) na capacidade do processo de remoção. A análise de DRX evidenciou que a MCM-41 apresentou uma estrutura mesoporosa bem definida. O espectro de IV confirmou a eficiência do CTABr como um modelo usado para direcionar a estrutura da peneira molecular MCM-41 em condições estáticas. A imagem obtida por MEV indicou aglomerados de forma irregular com aspecto esponjoso. Valores de até 94,0 % de eficiência de remoção e 4,22 mg/g de capacidade de remoção foram alcançados nos ensaios, indicando que o uso da MCM-41 tem grande potencial na remoção do corante amarelo.References
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